In-Line Measurement of Water Contents in Ethanol Using a Zeolite-Coated Quartz Crystal Microbalance

نویسندگان

  • Byoung Chul Kim
  • Takuji Yamamoto
  • Young Han Kim
چکیده

A quartz crystal microbalance (QCM) was utilized to measure the water content in ethanol. For the improvement of measurement sensitivity, the QCM was modified by applying zeolite particles on the surface with poly(methyl methacrylate) (PMMA) binder. The measurement performance was examined with ethanol of 1% to 5% water content in circulation. The experimental results showed that the frequency drop of the QCM was related with the water content though there was some deviation. The sensitivity of the zeolite-coated QCM was sufficient to be implemented in water content determination, and a higher ratio of silicon to aluminum in the molecular structure of the zeolite gave better performance. The coated surface was inspected by microscopy to show the distribution of zeolite particles and PMMA spread.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

In-Line Measurement of Water Content in Ethanol Using a PVA-Coated Quartz Crystal Microbalance

An in-line device for measuring the water content in ethanol was developed using a polyvinyl alcohol (PVA)-coated quartz crystal microbalance. Bio-ethanol is widely used as the replacement of gasoline, and its water content is a key component of its specifications. When the PVA-coated quartz crystal microbalance is contacted with ethanol containing a small amount of water, the water is absorbed...

متن کامل

Molecular recognition on acoustic wave devices: zeolite thin films coated with organosilane gate layers

Microporous thin films composed of a molecular coupling layer, zeolite crystals, and a porous silica overlayer, were formed on the gold electrodes of quartz crystal microbalances (QCMs). The silica overlayer enhances the mechanical stability of the zeolite films, and results in additional surface area and porosity as characterized by the sorption isotherms and transient sorption of vapors with ...

متن کامل

Multichannel monolithic quartz crystal microbalance gas sensor array.

Multichannel Monolithic Quartz Crystal Microbalance (MQCM), in which an array of electrodes is fabricated on a monolithic quartz wafer, is a very attractive approach for miniaturization using Micro-Electro-Mechanical Systems(MEMS) technology for high throughput chemical or biological sensor systems. In this paper, we demonstrate and validate a monolithic QCM sensor array for gas detections. The...

متن کامل

Polymer-Based Micro-Sensor Paired Arrays for the Determination of Primary Alcohol Vapors

An artificial olfactory system (or “electronic nose”) has been developed to investigate the interactions between polymer-modified sensors with odorant vapors from the headspace of primary alcohol samples. Complementary pairs of polymer-coated quartz crystal microbalance sensors and polymer/carbon black-coated microresistance sensors have been used to produce a characteristic value for the odora...

متن کامل

Transformation Characterization of Ni(OH)2/NiOOH in Ni-Pt Films Using an Electrochemical Quartz Crystal Microbalance for Ethanol Sensors

The transformation characterization of Ni(OH)2/NiOOH in Ni-Pt films was investigated using an electrochemical quartz crystal microbalance (EQCM) in an alkaline electrolyte under various experiment conditions. The Ni-Pt films were prepared by electro-deposition on gold-coated quartz crystal chips. When cyclic voltammetry (CV) was performed continually, the OH ions diffused into the Ni-Pt film to...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 15  شماره 

صفحات  -

تاریخ انتشار 2015